| 1. Freddie Sees the 'Midas' Guards | not rated | 0:59 |
| 2. Main Titles | not rated | 0:47 |
| 3. Search Continues by 'Midas' Guards | not rated | 1:47 |
| 4. The Airport Chase / Resume Freddie | not rated | 1:59 |
| 5. Professor Turner and Obsession with Gold | not rated | 0:55 |
| 6. Turner/Purdie and Gambit Give Chase | not rated | 2:42 |
| 7. Walk Away | not rated | 0:31 |
| 8. Red Mask Party Music (with sound effects) | not rated | 1:49 |
| 9. Contamination | not rated | 0:12 |
| 10. Freddie's Death, Driving over Cliff | not rated | 2:27 |
| 11. Purdey at Pilton Down | not rated | 0:31 |
| 12. Purdey, a Prisoner | not rated | 1:00 |
| 13. Three to the Rescue | not rated | 0:51 |
| 14. End Titles | not rated | 0:32 |
| 15. Eastern Block Border (1960) | not rated | 1:54 |
| 16. The Trapeze | not rated | 0:16 |
| 17. Main Titles | not rated | 0:48 |
| 18. Episode Title | not rated | 0:15 |
| 19. Gunner Hit by Swing - Flashback | not rated | 0:33 |
| 20. Gunner at the Farm | not rated | 0:26 |
| 21. Gunner on the Move | not rated | 0:23 |
| 22. Gunner Hit by Ball | not rated | 0:12 |
| 23. Gunner Outside Church | not rated | 0:27 |
| 24. Flyer Arrives at Church | not rated | 0:21 |
| 25. Flyer at the Second Church | not rated | 1:08 |
| 26. Gunner Runs for It | not rated | 0:42 |
| 27. Gunner on the Phone | not rated | 0:28 |
| 28. Purdey on the Trail | not rated | 0:24 |
| 29. Purdey Attacks Cromwell | not rated | 0:21 |
| 30. Gunner Watching from Tree | not rated | 0:29 |
| 31. Purdey in Her Flat | not rated | 0:27 |
| 32. Aftermath | not rated | 0:29 |
| 33. Derelict Picture Palace | not rated | 1:01 |
| 34. Cromwell in the Shadows | not rated | 1:07 |
| 35. Gun Drawn on Purdey | not rated | 0:31 |
| 36. Cromwell Shoots Gunner - End of Episode | not rated | 0:17 |
| 37. End Titles | not rated | 0:32 |
| 38. Mike Gambit's 'Pop Fans' Drilled by Purdey | not rated | 0:52 |
| 39. Pop Fans Riot and Vasil Is Rescued | not rated | 0:34 |
| 40. Main Titles | not rated | 0:48 |
| 41. Episode Title | not rated | 0:14 |
| 42. Perov's Suicide | not rated | 0:53 |
| 43. Mock Funeral at Crematorium | not rated | 1:29 |
| 44. The Plot Thickens | not rated | 2:17 |
| 45. Miller Arrives at Steed's Home | not rated | 0:57 |
| 46. Gambit and Spence's Judo Fight | not rated | 1:21 |
| 47. The Bishop Despatches His Attacker | not rated | 0:16 |
| 48. Purdey Investigates | not rated | 0:38 |
| 49. Steed's Date | not rated | 0:37 |
| 50. Olga with Gun, Disarmed by Steed | not rated | 2:01 |
| 51. Crematorium | not rated | 0:55 |
| 52. Perov Plots to Kill Purdey | not rated | 0:20 |
| 53. Purdey's Flat | not rated | 0:48 |
| 54. Gambit to the Rescue | not rated | 1:24 |
| 55. Purdey Triumphs over Perov | not rated | 0:56 |
| 56. End Titles | not rated | 0:32 |
| 57. The Cybernaut Attacks (with sound effects) | not rated | 0:59 |
| 58. Tale of the Big Why | not rated | 3:24 |
| 59. Obsession | not rated | 3:30 |
| 60. Cat Amongst the Pigeons | not rated | 2:53 |
| 61. A Flavour of the New Avengers | not rated | 7:04 |
| 62. The New Avengers - End Titles | not rated | 2:20 |
| 1:09:07 |
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