| 1. Original Recording - ATV (Opening Logo) | not rated | 0:11 |
| 2. The Cyril Stapleton Orchestra, Cox/Jacqui McShee/Jansch/Renbourn/Thompson - Department S | not rated | 2:53 |
| 3. Geoff Love & His Orchestra, Roger Webb - Strange Report | not rated | 2:04 |
| 4. Ron Grainer & His Orchestra, Barry Gray - Man in a Suitcase | not rated | 2:11 |
| 5. The Tony Hatch Orchestra, Ron Grainer - The Champions | not rated | 2:07 |
| 6. The Bob Leaper Orchestra, B. Gray - Dangerman Theme (High Wire) | not rated | 1:48 |
| 7. Edwin Astley - Randall & Hopkirk (Deceased) | not rated | 3:04 |
| 8. The John Barry Orchestra, Barry - The Adventurer | not rated | 2:07 |
| 9. Laurie Johnson, Laurie Johnson - Jason King Theme | not rated | 2:03 |
| 10. John Barry, J.J. Barry - The Persuaders Theme | not rated | 2:13 |
| 11. Ron Grainer, Ron Grainer - The Prisoner | not rated | 2:19 |
| 12. Brian Fahey - The Baron | not rated | 1:48 |
| 13. Tony Christie - The Protectors | not rated | 3:18 |
| 14. Tony Hatch & His Orchestra, Green - Ghost Squad | not rated | 2:12 |
| 15. Cyril Stapleton & The Eliminators, Peter Knight - The Saint | not rated | 2:47 |
| 16. Saint Orchestra, Dee/Martin - Return of The Saint | not rated | 2:50 |
| 17. Barry Gray, Barry Gray - U.F.O. | not rated | 2:10 |
| 18. Barry Gray, Barry Gray - Space 1999 | not rated | 2:03 |
| 40:08 |
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