| 1. Luciano Pavarotti, Various - 'o Sole Mio | not rated | 3:30 |
| 2. Russell Watson; Mark Smith: Royal Philharmonic Orchestra, Ennio Morricone - Morricone: Nella Fantasia | not rated | 4:31 |
| 3. Katherine Jenkins, Various - Time To Say Goodbye | not rated | 4:01 |
| 4. Jonas Kaufmann, Various - E Lucevan Le Stelle | not rated | 3:20 |
| 5. Hayley Westenra, Giacomo Puccini - Puccini: Gianni Schicchi - O Mio Babbino Caro | not rated | 2:37 |
| 6. Renée Fleming; Charles Mackerras: London Philharmonic Orchestra, Giacomo Puccini - Puccini: Madama Butterfly - Un Bel Dì, Vedremo | not rated | 4:56 |
| 7. Vittorio Grigolo, Various - Maria | not rated | 3:01 |
| 8. Plácido Domingo, Various - Be My Love | not rated | 3:16 |
| 9. Sarah Brightman, Plácido Domingo, Etc.; Lorin Maazel: English Chamber Orchestra, Andrew Lloyd Webber - Lloyd Webber: Requiem - Pie Jesu | not rated | 4:01 |
| 10. José Carreras, Various - Core 'ngrato | not rated | 3:13 |
| 11. Joan Sutherland, Huguette Tourangeau; Richard Bonynge: Orchestre De La Suisse Ro, Jacques Offenbach - Offenbach: Les Contes D'Hoffmann - Belle Nuit, O Nuit D'Amour (Barcarolle) | not rated | 4:12 |
| 12. Anna Netrebko; Gianandrea Noseda: Vienna Philharmonic Orchestra, Vienna State Op, Antonin Dvorák - Dvorák: Rusalka - Mesicku Na Nebi Hlubokém (Song To The Moon) | not rated | 5:06 |
| 13. Angela Gheorghiu, Alfredo Catalani - Catalani: La Wally - Largo Al Factotum | not rated | 3:43 |
| 14. Roberto Alagna, Various - Your Tiny Hand Is Frozen | not rated | 4:44 |
| 15. Heitor Pereira, Lisa Gerrard, Hans Zimmer, Etc., Hans Zimmer - Zimmer/Gerrard: Gladiator - Now We Are Free | not rated | 4:23 |
| 16. Montserrat Caballé, Various - Vissi D'arte | not rated | 3:41 |
| 17. Juan Diego Flórez, Various - Una Furtiva Lagrima | not rated | 4:44 |
| 18. Kiri Te Kanawa; Jeffrey Tate: English Chamber Orchestra, Joseph Canteloube - Canteloube: Songs Of The Auvergne, Series 1 - #2, "Baïlèro" | not rated | 6:47 |
| 19. Bryn Terfel, Various - Il Mio Cuore Va (My Heart Will Go On) | not rated | 3:38 |
| 20. Joan Sutherland, Luciano Pavarotti, Etc.; Zubin Mehta: London Philharmonic Orche, Giacomo Puccini - Puccini: Turandot - Act 3: Nessun Dorma! | not rated | 2:59 |
| 1:20:33 |
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